Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 14-15, Pages 2643-2647Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100315
Keywords
alkenes; nitration; nitrites; oxygenation; radical reactions
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan
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A method for the oxidative nitration of alkenes using a combination of tert-butyl nitrite and molecular oxygen to give beta-nitro alcohols and their nitrate derivatives has been developed. The present reaction provides a practical method for the synthesis of nitro compounds because of the mild reaction conditions, the use of inexpensive reagents and a simple experimental procedure.
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