Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 16, Pages 2939-2944Publisher
WILEY-BLACKWELL
DOI: 10.1002/adsc.201100334
Keywords
C?H functionalization; chiral spiro ligands; indoles; iron
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Funding
- National Natural Science Foundation of China
- National Basic Research Program of China (973 Program) [2010CB833300, 2011CB808600]
- Ministry of Education of China [B06005]
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An easily available iron catalyst was developed to accomplish the C?H functionalization of indoles with a-aryl-a-diazoesters in high yields under mild conditions. The asymmetric C?H functionalization of indoles was also realized by using iron complexes of chiral spiro bisoxazolines with up to 78% ee.
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