Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 4, Pages 606-616Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000591
Keywords
aerobic oxidation; alcohols; aldehydes; catalyst recycling; heterogeneous catalysis
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Funding
- Council of Scientific and Industrial Research, India
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Nanocrystalline magnesium oxide-stabilized palladium(0) [NAP-Mg-Pd(0)], as an efficient catalytic system has been employed for the selective oxidation of alcohols using atmospheric oxygen as a green oxidant at room temperature. Various alcohols could be transformed into their corresponding aldehydes or ketones in good to excellent yields using a set of optimal conditions. NanoActive (TM) Magnesium Oxide Plus, [NAP-MgO] with its three-dimensional structure and well-defined shape acts as an excellent support for well dispersed palladium(0) nanoparticles. This catalyst can be recovered and reused for several cycles without any significant loss of catalytic activity.
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