Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 2-3, Pages 401-410Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000580
Keywords
4H-3,1-benzoxazin-4-ones; oxidation; peroxides; potassium iodide; 3H-quinazolin-4-ones
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Funding
- Council of Scientific and Industrial Research (CSIR), New Delhi
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A simple and elegant method for benzylic activation was demonstrated employing the potassium iodide/tert-butyl hydrogen peroxide catalytic system. This methodology was further extended for the synthesis of biologically important heterocycles namely, 3H-quinazolin-4-ones and 4H-3,1-benzoxazin-4-ones including mecloqualone and etaqualone which are important quinazolinone-based drugs used for the treatment of insomnia in good yields.
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