Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 8, Pages 1359-1366Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100109
Keywords
aryl-gold(I) species; decarboxylation; gold; halogenation; homogeneous catalysis; silver
Categories
Funding
- Engineering and Physical Sciences Research Council
- Royal Society
- EPSRC National Mass Spectrometry Service (Swansea), QMUL
- Nuffield Foundation
- EPSRC [EP/G031649/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G031649/1] Funding Source: researchfish
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Gold(I) salts are found to mediate the decarboxylation of a variety of aromatic and heteroaromatic carboxylic acids at significatively lower temperatures (as low as 60 degrees C) than the currently used copper(I) (180-190 degrees C) and silver(I) (80-140 degrees C) systems. In contrast to silver(I)-and copper(I)-mediated decarboxylations, the resulting aryl-gold(I) complexes are stable towards protodemetallation and can be readily isolated.
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