Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 11-12, Pages 2111-2118Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100065
Keywords
alkynes; annulation; benzylic alcohols; iron trichloride; polysubstituted indenes
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Funding
- NNSF of China [2009CB825300]
- Shanghai Science and Technology Committee [08dj1400100]
- Research Fund for the Doctoral Program of Higher Education of China
- Shanghai Leading Academic Discipline Project [B108]
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A convenient and efficient method for the synthesis of polysubstituted indenes has been developed by the iron(III) trichloride-catalyzed tandem mono- and dibenzylation/cyclization reactions of benzylic alcohols with alkynes. This method is featured with the easily available starting materials, cheap catalyst, simple manipulation and mild conditions.
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