4.7 Article

Facile Preparation of 2-Substituted Benzoxazoles and Benzothiazoles via Aerobic Oxidation of Phenolic and Thiophenolic Imines Catalyzed by Polymer-Incarcerated Platinum Nanoclusters

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 17, Pages 3085-3089

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100430

Keywords

nanoparticles; oxidation; platinum; polymers; supported catalysis

Funding

  1. Japan Society for the Promotion of Science (JSPS)
  2. University of Tokyo
  3. MEXT (Japan)
  4. NEDO
  5. Grants-in-Aid for Scientific Research [21225002, 09F09765, 22750032, 22106507] Funding Source: KAKEN

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Platinum nanoclusters supported on a polymer/carbon black composite material was found to be an excellent catalyst for the oxidative cyclization of phenolic and thiophenolic Schiff bases to 2-substituted benzoxazoles and benzothiazoles under ambient conditions.

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