Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 2-3, Pages 263-267Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000792
Keywords
aminophosphonates; hydrophosphonylation; nickel catalysis; ynamides
Categories
Funding
- CNRS
- University Paris-Sud 11
- University of Versailles Saint-Quentin en Yvelines
- ANR
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A highly regio- and stereoselective, nickel(II)-catalyzed procedure for the hydrophosphonylation of ynamides has been developed. This protocol provides a straightforward and efficient entry to a series of beta-aminovinylphosphonates that can easily be prepared in good yields from a wide range of ynamides and dialkyl phosphites as well as useful insights into the reactivity of ynamides under nickel catalysis.
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