Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 11-12, Pages 1993-2002Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100053
Keywords
fluorinated aromatic hydrocarbons; microwave irradiation; N-heterocyclic carbenes; olefin metathesis; ruthenium
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Funding
- Foundation for Polish Science
- European Union [Ventures/2008-1/5]
- CNRS
- Ministere de la Recherche
- Bretagne-Valorisation
- Rennes-Metropole
- Region Bretagne
- European Community [CP-FP 211468-2 EUMET]
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High conversions in ruthenium-based olefin metathesis of demanding substrates are commonly forced by using a high loading of a catalyst and conducting reactions at elevated temperature for extended times. However, in many cases this approach is not fully effective. In this article we present that fluorinated aromatic hydrocarbons (FAH) combined with microwave (MW) irradiation using a commercially available ruthenium-based pre-catalyst creates attractive reaction conditions for promoting challenging olefin metathesis transformations.
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