4.7 Article

Ligand-Free Reusable Palladium-Catalyzed Heck-Type Coupling Reactions of Hypervalent Iodine Reagents under Mild Conditions

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 7, Pages 1061-1066

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100008

Keywords

aryl halides; coupling reactions; hypervalent iodine reagents; olefins; palladium catalysis

Funding

  1. Natural Science Foundation of China [20802046]
  2. International S&T Cooperation Program of Jiangsu Province [BZ2010048]
  3. Key Laboratory of Organic Synthesis of Jiangsu Province

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Highly effective palladium-catalyzed Heck-type couplings of hypervalent iodine reagents are reported for the first time. It is noteworthy that such reactions could be carried out in the absence of ligand at 40 degrees C and the catalytic system could be easily reused for five times.

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