Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 2-3, Pages 287-290Publisher
WILEY-BLACKWELL
DOI: 10.1002/adsc.201000753
Keywords
alkynes; bond formation; gold; green chemistry; immobilization
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Funding
- MEXT
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [22790015] Funding Source: KAKEN
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Polystyrene-immobilized cationic gold catalysts 2a and 2b were synthesized for the first time and found to be highly effective catalysts for the bond-forming reactions via the activation of the C C triple bonds. The immobilized 2a was easily and quantitatively recovered from the reaction mixture and reused at least seven times while maintaining the original catalytic activity. Furthermore, a flow reactor containing 2a was developed for a larger scale continuous production.
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