Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 16, Pages 2927-2932Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100358
Keywords
Heck reaction; metallic glass; nanoporous materials; palladium; skeleton catalyst
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Japan Society for the Promotion of Science
- Grants-in-Aid for Scientific Research [23245020] Funding Source: KAKEN
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Nanoporous metallic glass palladium (PdNPore), which was fabricated by de-alloying of a glassy metallic alloy Pd30Ni50P20, exhibited a remarkable catalytic activity for the Heck reaction of versatile aryl iodides and aryl bromides. Moreover, the PdNPore can be reused several times without a significant loss of catalytic activity, and the PdNPore has ahigher resistance to leaching than palladium black and palladium on carbon.
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