Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 11-12, Pages 1883-1888Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100361
Keywords
catalysis; hydrophosphinylation; palladium; phenyl-H-phosphinates; H-phosphinic acids
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Funding
- National Science Foundation [CHE-0953368]
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The first metal-catalyzed hydrophosphinylation of unsaturated hydrocarbons with H-phosphinic acids is described. A strategy to activate the P-H bond through control of the tautomeric equilibrium using ethylene glycol is described. The reactions also avoid chromatographic purification.
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