Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 18, Pages 3347-3351Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100632
Keywords
amination; amino alcohols; cyclization; ene reaction; oxidation
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Funding
- Loughborough University
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A mild, simple oxidation protocol employing iron(III) chloride as a catalyst and hydrogen peroxide as a stoichiometric oxidant was found to be compatible with an intramolecular carbonyl nitroso ene reaction and allowed us to efficiently convert hydroxamic acids into a diverse range of 1,2- and 1,3-amino alcohol derivatives in a single operation.
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