4.7 Article

New Palladium-Catalyzed Cascades: 4-exo-dig Cyclocarbopalladation Reaction Followed by Suzuki-Miyaura or Sonogashira Cross-Coupling

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 353, Issue 17, Pages 3151-3156

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100465

Keywords

cascade reactions; cyclocarbopalladation; Sonogashira reaction; step economy; Suzuki-Miyaura reaction

Funding

  1. CNRS
  2. ANR
  3. Prestwick chemical
  4. MNERT

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Herein we describe new accesses to dienynes and trienynes using new cascade reactions: 4-exo-dig cyclocarbopalladation followed by a Suzuki-Miyaura or Sonogashira cross-coupling.

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