Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 2-3, Pages 243-279Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900797
Keywords
asymmetric synthesis; biomimetic synthesis; organocatalysis; organosilicon species; stereoselectivity
Categories
Funding
- National Natural Science Founder of China [20973051]
- Zhejiang Provincial Natural Science Foundation of China [Y4090139]
Ask authors/readers for more resources
Recent years have witnessed an explosive growth in the field of amino organocatalysis, especially in asymmetric enamine and iminium catalysis. Except for the obvious interaction between organocatalyst and substrate, the impact of bulky side group ons stereoselectivity is not as simple as one Could imagine. Within the development of bulky site-stereoselective organocatalysts, functional silyl organocatalysts with a bulky silicon group are promising and meet the high standards of modern synthetic methods. This review focuses on the recent advances in the synthetic applications of silicon-based, bulky amino organocatalysts in which catalysts containing an organosilicon moiety or group play a formative role in controlling both the course of the reaction as well as the stereoselectivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available