Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 17, Pages 2892-2898Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000575
Keywords
arylation; catalysis; cross-coupling; dimethyl sulfoxide/potassium hydroxide (DMSO/KOH); superbase; transition metal-free conditions
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Funding
- Fonds der Chemischen Industrie
- Excellence Initiative of the German federal and state governments
- RWTH Aachen University
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Potassium hydroxide (KOH) in dimethyl sulfoxide (DMSO) forms a superbasic medium that allows one to access cross-coupling products from reactions between aryl halides with various sulfur-, oxygen- and nitrogen-based nucleophiles under transition metal-free conditions.
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