Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 16, Pages 2783-2786Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000515
Keywords
asymmetric catalysis; chiral nickel complexes; alpha-chloro-beta-keto esters; electrophilic fluorination
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The catalytic enantioselective electrophilic fluorination promoted by chiral nickel complexes is described. The treatment of alpha-chloro-beta-keto esters with Selectfluor under mild reaction conditions afforded the corresponding fluorinated alpha-chloro-beta-keto esters with excellent enantioselectivities (up to 99% ee).
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