Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 18, Pages 3208-3214Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000637
Keywords
click chemistry; copper nanoparticles; cycloaddition; heterogeneous catalysis; triazoles; water
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Funding
- Spanish Ministerio de Ciencia e Innovacion (MICINN) [CTQ2007-65218, 2010-CSD2007-00006]
- Generalitat Valenciana (GV) [PROMETEO/2009/039]
- Vicerrectorado de Investigacion, Desarrollo e Innovacion of the Universidad de Alicante
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Copper nanoparticles on activated carbon have been found to effectively catalyze the multicomponent synthesis of 1,2,3-triazoles from different azide precursors, such as organic halides, diazonium salts, anilines and epoxides in water. The first one-pot transformation of an olefin into a triazole is also described. The catalyst is easy to prepare, very versatile and reusable at a low copper loading.
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