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A highly efficient and practical method for catalytic asymmetric vinylogous Mannich (AVM) reactions
Emma L. Carswell et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)
Recent applications of chiral ferrocene ligands in asymmetric catalysis
Ramon Gomez Arrayas et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)
An efficient enantiopure synthesis of a pivotal precursor to substance P antagonists
TC Nugent et al.
ORGANIC PROCESS RESEARCH & DEVELOPMENT (2006)
Chiral diphosphine ddppm-iridium complexes: Effective asymmetric imine hydrogenations at ambient pressures
A Dervisi et al.
ADVANCED SYNTHESIS & CATALYSIS (2006)
Multicomponent one-pot procedure for the synthesis of free α-chiral amines from aldehydes
A Côté et al.
JOURNAL OF ORGANIC CHEMISTRY (2005)
Efficient N-p-methoxyphenyl amine deprotection through anodic oxidation
SD Marin et al.
JOURNAL OF ORGANIC CHEMISTRY (2005)
Transfer hydrogenation of α-branched ketimines:: Enantioselective synthesis of cycloalkylamines via dynamic kinetic resolution
A Ros et al.
ADVANCED SYNTHESIS & CATALYSIS (2005)
A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis
A Leitner et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Evolution of titanium(IV) alkoxides and Raney nickel for asymmetric reductive amination of prochiral aliphatic ketones
TC Nugent et al.
ORGANIC LETTERS (2005)
Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex
KA Nolin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Enantioselective Bronsted acid catalyzed transfer hydrogenation: Organocatalytic reduction of imines
M Rueping et al.
ORGANIC LETTERS (2005)
Asymmetric synthesis of 1-substituted-1-(pyridin-2-yl)methylamines by diastereoselective reduction of enantiopure N-p-toluenesulfinyl ketimines
G Chelucci et al.
TETRAHEDRON LETTERS (2005)
Modular monodentate phosphoramidite ligands for rhodium-catalyzed enantioselective hydrogenation
Y Liu et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Chiral N-acylhydrazones:: Versatile imino acceptors for asymmetric amine synthesis
GK Friestad
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2005)
N-phosphinoylimines:: An emerging class of reactive intermediates for stereoselective organic synthesis
SM Weinreb et al.
SYNTHESIS-STUTTGART (2005)
Enantioselective synthesis of 2-substituted tetrahydro-β-carboline derivatives via the asymmetric transfer hydrogenation
P Roszkowski et al.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2005)
Asymmetric hydrogenation of imines catalyzed by iridium complexes with phosphine-phosphite ligands:: importance of backbone flexibility
S Vargas et al.
TETRAHEDRON LETTERS (2005)
New unsymmetrical hybrid ferrocenylphosphine-phosphoramidite ligands derived from H8-BINOL for highly efficient Rh-catalyzed enantioselective hydrogenation
QH Zeng et al.
TETRAHEDRON-ASYMMETRY (2005)
Preparation of enamides via palladium-catalyzed amidation of enol tosylates
A Klapars et al.
ORGANIC LETTERS (2005)
Aerobic oxidative amination of unactivated alkenes catalyzed by palladium
JL Brice et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Synthesis and highly enantioselective hydrogenation of exocyclic enamides:: (Z)-3-arylidene-4-acetyl-3,4-dihydro-2H-1,4-benzoxazines
YG Zhou et al.
JOURNAL OF ORGANIC CHEMISTRY (2005)
Monophosphite ligands derived from carbohydrates and H8-BINOL:: highly enantioselective Rh-catalyzed asymmetric hydrogenations
HM Huang et al.
TETRAHEDRON-ASYMMETRY (2005)
PipPhos and MorfPhos: Privileged monodentate phosphoramidite ligands for rhodium-catalyzed asymmetric hydrogenation
H Bernsmann et al.
JOURNAL OF ORGANIC CHEMISTRY (2005)
Diastereoselective and enantioselective Rh(l)-catalyzed additions of arylboronic acids to N-tert-butanesulfinyl and N-diphenylphosphinoyl aldimines
DJ Weix et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Approaching highly enantioselective reductive amination
VI Tararov et al.
SYNLETT (2005)
A novel highly selective chiral auxiliary for the asymmetric synthesis of L- and D-α-amino acid derivatives via a multicomponent Ugi reaction
A Basso et al.
JOURNAL OF ORGANIC CHEMISTRY (2005)
A general method for the preparation of N-sulfonyl aldimines and ketimines
JLG Ruano et al.
ORGANIC LETTERS (2005)
Ionic liquid-promoted, highly regioselective heck arylation of electron-rich olefins by aryl halides
J Mo et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Recent advances in catalytic asymmetric addition to imines and related C=N systems
T Vilaivan et al.
CURRENT ORGANIC CHEMISTRY (2005)
Asymmetric hydrogenation of aromatic compounds
F Glorius
ORGANIC & BIOMOLECULAR CHEMISTRY (2005)
N-acylhydrazones as versatile electrophiles for the synthesis of nitrogen-containing compounds
M Sugiura et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)
Diphenylphosphanylsulfoximines as ligands in iridium-catalyzed asymmetric imine hydrogenations
C Moessner et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)
A powerful bronsted acid catalyst for the organocatalytic asymmetric transfer hydrogenation of imines
S Hoffmann et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)
Enantioselective hydrogenation of alkenes and imines by a gold catalyst
C Gonzalez-Arellano et al.
CHEMICAL COMMUNICATIONS (2005)
Photosensitized reactions of oxime ethers: A steady-state and laser flash photolysis study
HJP de Lijser et al.
JOURNAL OF ORGANIC CHEMISTRY (2004)
Catechol-based phosphoramidites: A new class of chiral ligands for rhodium-catalyzed asymmetric hydrogenations
R Hoen et al.
ORGANIC LETTERS (2004)
Copper(I)-catalyzed asymmetric hydrosilylations of imines at ambient temperatures
BH Lipshutz et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)
A new highly chemoselective isomerization of allylamides
B Neugnot et al.
TETRAHEDRON (2004)
A novel class of P-O monophosphite ligands derived from D-mannitol: Broad applications in highly enantioselective Rh-catalyzed hydrogenations
HM Huang et al.
JOURNAL OF ORGANIC CHEMISTRY (2004)
Direct reductive amination versus hydrogenation of intermediates -: A comparison
VI Tararov et al.
ADVANCED SYNTHESIS & CATALYSIS (2004)
Highly enantioselective asymmetric hydrogenation of α-phthalimide ketone:: An efficient entry to enantiomerically pure amino alcohols
AW Lei et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
A practical, solvent free, one-pot synthesis of C2-symmetrical secondary amines
A Alexakis et al.
TETRAHEDRON LETTERS (2004)
Chemoselective reductive alkylation of ammonia with carbonyl compounds: synthesis of primary and symmetrical secondary amines
B Miriyala et al.
TETRAHEDRON (2004)
Rationalising the effect of reducing agent on the oxazaborolidine-mediated asymmetric reduction of N-substituted imines
EHM Kirton et al.
TETRAHEDRON LETTERS (2004)
New efficient synthesis of Taniaphos ligands: application in ruthenium- and rhodium-catalyzed enantioselective hydrogenations
K Tappe et al.
TETRAHEDRON-ASYMMETRY (2004)
Unsymmetrical hybrid ferrocene-based phosphine-phosphoramidites: A new class of practical Ligands for Rh-catalyzed asymmetric hydrogenation
XP Hu et al.
ORGANIC LETTERS (2004)
Olefins as steering ligands for homogeneously catalyzed hydrogenations
P Maire et al.
CHEMISTRY-A EUROPEAN JOURNAL (2004)
Self-supported heterogeneous catalysts for enantioselective hydrogenation
XW Wang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
On the mechanism of stereoselection in Rh-catalyzed asymmetric hydrogenation: A general approach for predicting the sense of enantioselectivity
ID Gridnev et al.
ACCOUNTS OF CHEMICAL RESEARCH (2004)
Aza-Baylis-Hillman reactions of N-(arylmethylene) diphenylphosphinamidies with activated olefins in the presence of various Lewis bases
M Shi et al.
ADVANCED SYNTHESIS & CATALYSIS (2004)
Synthesis of Nα-(1-phenyl-2-mercaptoethyl) amino acids, new building blocks for ligation and cyclization at non-cysteine sites:: Scope and limitations in peptide synthesis
S Tchertchian et al.
JOURNAL OF ORGANIC CHEMISTRY (2004)
Enantioselective hydrogenation of imines in ionic liquid/carbon dioxide media
M Solinas et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
A complementary method to obtain N-acyl enamides using the Heck reaction:: extending the substrate scope for asymmetric hydrogenation
P Harrison et al.
TETRAHEDRON LETTERS (2004)
Efficient enantioselective hydrogenation of arylimines using aminophosphine-oxazoline iridium catalysts
C Blanc et al.
TETRAHEDRON-ASYMMETRY (2004)
Chiral monodentate phosphorus ligands for rhodium-catalyzed asymmetric hydrogenation
T Jerphagnon et al.
TETRAHEDRON-ASYMMETRY (2004)
Development of DIOP derivatives as efficient ligands for asymmetric hydrogenation: factors controlling the reactivities and enantioselectivities
DA Liu et al.
TETRAHEDRON-ASYMMETRY (2004)
Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands
Y Fu et al.
JOURNAL OF ORGANIC CHEMISTRY (2004)
Enantioselective hydrogenation of trimethylindolenine in ionic liquids
R Giernoth et al.
ADVANCED SYNTHESIS & CATALYSIS (2004)
Asymmetric synthesis of isoquinoline alkaloids
M Chrzanowska et al.
CHEMICAL REVIEWS (2004)
The first catalytic inverse-electron demand hetero-Diels-Alder reaction of nitroso alkenes using pyrrolidine as an organocatalyst
TC Wabnitz et al.
ORGANIC & BIOMOLECULAR CHEMISTRY (2004)
Role of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilane
AV Malkov et al.
ORGANIC LETTERS (2004)
Persistent N-chirality as the only source of asymmetry in nonracemic N2PdCl2 complexes
KA Pelz et al.
ORGANOMETALLICS (2004)
Rh(I)-catalyzed solvent-free ortho-alkylation of aromatic imines under microwave irradiation
G Vo-Thanh et al.
TETRAHEDRON (2004)
Optically active 1,1′-Di-tert-butyl-2,2′-diphosphetanyl and its application in rhodium-catalyzed asymmetric hydrogenations
T Imamoto et al.
SYNTHESIS-STUTTGART (2004)
Practical synthesis of optically active fluorine-substituted α-phenylethylamines by retardation of hydrogenolytic cleavage at benzylic position
M Kanai et al.
CHEMISTRY LETTERS (2004)
Industrial methods for the production of optically active intermediates
M Breuer et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)
Application of phosphine-oxazoline ligands in Ir-catalyzed asymmetric hydrogenation of acyclic aromatic N-arylimines
A Trifonova et al.
ORGANIC LETTERS (2004)
Formation of enamides via palladium(II)-catalyzed vinyl transfer from vinyl ethers to nitrogen nucleophiles
JL Brice et al.
ORGANIC LETTERS (2004)
CuI/N,N-dimethylglycine-catalyzed coupling of vinyl halides with amides or carbamates
XH Pan et al.
ORGANIC LETTERS (2004)
Highly selective asymmetric hydrogenation using a three hindered quadrant bisphosphine rhodium catalyst
G Hoge et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
Reduction and reductive coupling of imines by Sm(II)-based reagents
M Kim et al.
TETRAHEDRON (2003)
Diastereoselective heterogeneous catalytic hydrogenation of aromatic or heteraromatic compounds
M Besson et al.
TOPICS IN CATALYSIS (2003)
Chiral monophosphites derived from carbohydrate: Conformational effect in catalytic asymmetric hydrogenation
HM Huang et al.
ORGANIC LETTERS (2003)
A one-pot process for the enantioselective synthesis of amines via reductive amination under transfer hydrogenation conditions
GD Williams et al.
ORGANIC LETTERS (2003)
Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites:: the substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation
SF Zhu et al.
TETRAHEDRON-ASYMMETRY (2003)
Enantioselective borohydride reduction catalyzed by optically active cobalt complexes
T Yamada et al.
CHEMISTRY-A EUROPEAN JOURNAL (2003)
Highly enantioselective hydrogenation of enamides catalyzed by rhodium-monodentate phosphoramidite complex derived from H8-BINOL
XS Li et al.
TETRAHEDRON-ASYMMETRY (2003)
β-isocupreidine-catalyzed asymmetric Baylis-Hillman reaction of imines
S Kawahara et al.
ORGANIC LETTERS (2003)
Stereocontrol in hydride addition to ketone-derived chiral N-acylhydrazones
J Qin et al.
TETRAHEDRON (2003)
New chiral phosphorus ligands for enantioselective hydrogenation
WJ Tang et al.
CHEMICAL REVIEWS (2003)
Asymmetric reduction of ketoxime derivatives and N-alkylketimines with borane-oxazaborolidine adducts
MP Krzeminski et al.
TETRAHEDRON-ASYMMETRY (2003)
Highly efficient rhodium/monodentate phosphoramidite catalyst and its application in the enantioselective hydrogenation of enamides and α-dehydroamino acid derivatives
X Jia et al.
JOURNAL OF ORGANIC CHEMISTRY (2003)
Synthesis of fluorinated 1-(3-morpholin-4-yl-phenyl)-ethylamines
YJ Wu et al.
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS (2003)
Highly enantioselective reductive amination of simple aryl ketones catalyzed by Ir-f-Binaphane in the presence of titanium(IV) isopropoxide and iodine
YX Chi et al.
JOURNAL OF ORGANIC CHEMISTRY (2003)
The first highly enantioselective homogeneously catalyzed asymmetric reductive amination:: Synthesis of α-N-benzylamino acids
R Kadyrov et al.
JOURNAL OF ORGANIC CHEMISTRY (2003)
Catalytic enantioselective Strecker reaction of ketoimines
S Masumoto et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
Application of monodentate secondary phosphine oxides, a new class of chiral ligands, in Ir(I)-catalyzed asymmetric imine hydrogenation
XB Jiang et al.
ORGANIC LETTERS (2003)
Highly regioselective hydrogenolysis of bis(α-methylbenzyl)amine derivatives affected by the trifluoromethyl substituent on the aromatic ring
M Kanai et al.
ORGANIC LETTERS (2003)
Novel enantioselective synthesis of both enantiomers of furan-2-yl Amines and amino acids
AS Demir et al.
HELVETICA CHIMICA ACTA (2003)
A new principle in combinatorial asymmetric transition-metal catalysis: Mixtures of chiral monodentate P ligands
MT Reetz et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)
Catalytic asymmetric hydrogenation in a room temperature ionic liquid using chiral Rh-complex of ionic liquid grafted 1,4-bisphosphine ligand
SG Lee et al.
CHEMICAL COMMUNICATIONS (2003)
Highly enantioselective hydrogen-transfer reductive amination: Catalytic asymmetric synthesis of primary amines
R Kadyrov et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)
New monodentate chiral phosphite ligands for asymmetric hydrogenation
P Hannen et al.
CHEMICAL COMMUNICATIONS (2003)
Enantioselective, copper(I)-catalyzed three-component reaction for the preparation of propargylamines
N Gommermann et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)
Diastereoselective hydrogenation in the preparation of fine chemicals
P Kukula et al.
TOPICS IN CATALYSIS (2003)
Synthesis of chiral trifluoromethylated amines by palladium-catalyzed diastereoselective hydrogenation-hydrogenolysis approach
B Torok et al.
ADVANCED SYNTHESIS & CATALYSIS (2003)
Monodentate phosphoramidites: A breakthrough in rhodium-catalysed asymmetric hydrogenation of olefins
M van den Berg et al.
ADVANCED SYNTHESIS & CATALYSIS (2003)
Ruthenium-catalysed enantioselective hydrogenation of trisubstituted enamides derived from 2-tetralone and 3-chromanone: Influence of substitution on the amide arm and the aromatic ring
JL Renaud et al.
ADVANCED SYNTHESIS & CATALYSIS (2003)
Iridium-catalyzed enantioselective hydrogenation of imines with xylose diphosphite and diphosphinite ligands
E Guiu et al.
ADVANCED SYNTHESIS & CATALYSIS (2003)
Enantioselective hydrogenation of imines using a diverse library of ruthenium dichloride(diphospbine)(diamine) precatalysts
CJ Cobley et al.
ADVANCED SYNTHESIS & CATALYSIS (2003)
Selective hydrogenation for fine chemicals: Recent trends and new developments
HU Blaser et al.
ADVANCED SYNTHESIS & CATALYSIS (2003)
Applications of tert-butanesulfinamide in the asymmetric synthesis of amines
JA Ellman
PURE AND APPLIED CHEMISTRY (2003)
Catalytic Leuckart-Wallach-type reductive amination of ketones
M Kitamura et al.
JOURNAL OF ORGANIC CHEMISTRY (2002)
Chiral C2-symmetric ligands with 1,4-dioxane back-bone derived from tartrates:: Syntheses and applications in asymmetric hydrogenation
WG Li et al.
JOURNAL OF ORGANIC CHEMISTRY (2002)
N-tert-Butanesulfinyl imines:: Versatile intermediates for the asymmetric synthesis of amines
JA Ellman et al.
ACCOUNTS OF CHEMICAL RESEARCH (2002)
Enantioselective hydrogenation of enamides catalyzed by chiral rhodium-monodentate phosphite complexes
MT Reetz et al.
TETRAHEDRON LETTERS (2002)
Recoverable catalysts for asymmetric organic synthesis
QH Fan et al.
CHEMICAL REVIEWS (2002)
Asymmetric reduction of azirines; a new route to chiral aziridines
P Roth et al.
CHEMICAL COMMUNICATIONS (2002)
Highly enantioselective hydrogenation of enamides catalyzed by rhodium-monodentate phosphoramidite complex
X Jia et al.
TETRAHEDRON LETTERS (2002)
Synthesis and first applications of a new family of chiral monophosphine ligand: 2,5-diphenylphosphospholanes
F Guillen et al.
TETRAHEDRON (2002)
An ortho-substituted BIPHEP ligand and its applications in Rh-catalyzed hydrogenation of cyclic enamides
WJ Tang et al.
ORGANIC LETTERS (2002)
Conformational studies by dynamic NMR. 89.1 stereomutation and cryogenic enantioseparation of conformational antipodes of hindered aryl oximes
F Gasparrini et al.
JOURNAL OF ORGANIC CHEMISTRY (2002)
Solvias Josiphos ligands: from discovery to technical applications
HU Blaser et al.
TOPICS IN CATALYSIS (2002)
Synthesis of optically-active benzylic amines; asymmetric reduction of ketoxime ethers with chiral oxazaborolidines
E Fontaine et al.
TETRAHEDRON-ASYMMETRY (2001)
Influence of HMPA on reducing power and reactivity of SmBr2
BW Knettle et al.
ORGANIC LETTERS (2001)
Asymmetric hydrogenation of enamides with Rh-BisP* and Rh-MiniPHOS catalysts. Scope, limitations, and mechanism
ID Gridnev et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Stereocontrolled synthesis of cis-dibenzoquinolizine chlorofumarates:: Curare-like agents of ultrashort duration
I Kaldor et al.
JOURNAL OF ORGANIC CHEMISTRY (2001)
First chemo- and stereoselective reduction of imines using trichlorosilane activated with N-formylpyrrolidine derivatives
F Iwasaki et al.
TETRAHEDRON LETTERS (2001)
RuHCl(diphosphine)(diamine): Catalyst precursors for the stereoselective hydrogenation of ketones and imines
K Abdur-Rashid et al.
ORGANOMETALLICS (2001)
Asymmetric synthesis of beta-haloaryl beta-amino acid derivatives
SD Bull et al.
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (2001)
Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines
I Takei et al.
CHEMICAL COMMUNICATIONS (2001)
Ligand substituent effects on asymmetric induction. Effect of structural variations of the DIOP ligand on the Rh-catalyzed asymmetric hydrogenation of enamides
YY Yan et al.
ORGANIC LETTERS (2000)
Highly enantioselective rhodium-catalyzed hydrogenation with monodentate ligands
M van den Berg et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
On the origin of opposite stereoselection in the asymmetric hydrogenation of phenyl- and tert-butyl-substituted enamides
ID Gridnev et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Enantioselective reduction of oxime ethers with borane catalyzed by polymer-supported 2-piperazinemethanol
S Itsuno et al.
JOURNAL OF ORGANIC CHEMISTRY (2000)
Synthesis of 3, 4-O-isopropylidene(3S,4S)-dihydroxy-(2R,5R)bis(diphenylphosphino)hexane and its application in Rh-catalyzed highly enantioselective hydrogenation of enamides
W Li et al.
JOURNAL OF ORGANIC CHEMISTRY (2000)
Asymmetric reduction of enantiopure imines with zinc borohydride: stereoselective synthesis of chiral amines
C Cimarelli et al.
TETRAHEDRON-ASYMMETRY (2000)
Heterogenised iridium complexes for the asymmetric hydrogenation of imines
R Margalef-Catalá et al.
TETRAHEDRON-ASYMMETRY (2000)
Rhodium(I) catalyzed asymmetric hydrogenation of enamines
VI Tararov et al.
TETRAHEDRON LETTERS (2000)
Diastereoselective LiAlH4 reduction of chiral ketone hydrazones derived from (R)-(-)-2-aminobutan-1-ol
P Bataille et al.
TETRAHEDRON-ASYMMETRY (2000)
A method for the asymmetric hydrosilylation of N-aryl imines
MC Hansen et al.
ORGANIC LETTERS (2000)
Efficient kinetic resolution in the asymmetric hydrosilylation of imines of 3-substituted indanones and 4-substituted tetralones
JS Yun et al.
JOURNAL OF ORGANIC CHEMISTRY (2000)
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