Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 13, Pages 2111-2115Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000502
Keywords
azides; biocatalysis; click chemistry; designer cells; halohydrin dehalogenase; reaction cascade
Categories
Funding
- Netherlands Ministry of Economic Affairs
- B-Basic partner organizations
- NWO-ACTS
- IBOS
- NWO-STW
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The multistep catalytic process using designer cells, either added as freshly prepared suspensions or as stable lyophilized powder, and click reaction can be performed in one pot. The sequence of four reactions allows the production of both enantiomers of beta-hydroxytriazoles with high enantiomeric excess.
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