Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 17, Pages 2943-2948Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000516
Keywords
allylic oxidation; tert-butyl hydroperoxide; heterogeneous catalysis; metal-organic frameworks; MIL-101; alpha,beta-unsaturated ketones
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Funding
- Russian Foundation for Basic Research (RFBR) [09-03-93109, 09-03-12112]
- Siberian Branch of Russian Academy of Sciences [107]
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The mesoporous metal-organic framework MIL-101 is an efficient heterogeneous catalyst for the selective allylic oxidation of alkenes with tert-butyl hydroperoxide. The selectivity towards alpha,beta-unsaturated ketones reaches 86-93%. The temperature of the catalyst activation strongly affects the ketone yield. MIL-101 is stable to chromium leaching, behaves as a true heterogeneous catalyst, can be easily recovered by filtration, and can be reused several times without loss of the catalytic performance.
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