Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 2-3, Pages 425-432Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900698
Keywords
coupling reactions; heterogenization; magnetic nanoparticles; palladium; phosphine ligands
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Funding
- Alexander volt Humboldt-Foundation
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An organic-inorganic hybrid heterogeneous nanocatalyst system was synthesized by covalent grafting a palladium dichloride complex of the type (L)(2)PdCl2 (L=trimethoxysilyl-functionalized triphenylphosphine) on silica-coated magnetic nanoparticles. It Is a highly active and recyclable catalyst for the Suzuki-Miyaura cross-coupling reaction. The new catalyst can easily be separated from the reaction mixture by applying an external magnetic field and can be recycled many times without any loss of activity.
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