Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 11-12, Pages 1955-1966Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000070
Keywords
asymmetric catalysis; catalyst design; enantioselectivity; palladium, thiourea-oxazoline library
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Funding
- National Science and Technology Major Project Development of key technologies for the combinatorial synthesis of privileged scaffolds [2009ZX09501-012]
- National Science Foundation of China [20325208, 20521202]
- Nanshan Science Technology [NANKEPING2007005]
- Royal Society
- EPSRC (UK)
- Royal Thai Government
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We report herein the synthesis of novel chiral S,N-heterobidentate thiourea-oxazoline ligands and their application to palladium-catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. Copper salts were found to play multiple roles in this reaction. Substituted 2-phenylsuccinates were obtained in >90% yield and up to 84% cc under optimized conditions.
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