Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 14-15, Pages 2432-2436Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000400
Keywords
Baylis-Hillman adducts; cascade reactions; copper; imidates; ketenimines; multicomponent reactions
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Funding
- National Natural Science Foundation of China [20872128, J0830413]
- Fundamental Research Funds for the Central Universities [2009QNA3011]
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4-(Alkoxycarbonyl)-pent-4-enimidates were regioselectively synthesized via a copper-catalyzed four-component reaction of Baylis-Hillman adducts with terminal alkynes, sulfonyl azides and alcohols. The procedure is concise, general and efficient. The resulting pentenimidates could be further transformed to 3-methylene-2,3-dihydroindene-1-imidates.
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