Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 352, Issue 4, Pages 711-717Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900747
Keywords
chalcones; Claisen-Schmidt condensation; green chemistry; heterogeneous catalysis; metal-organic frameworks
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Funding
- Spanish DGI [CTQ06-6857, CTQ2007-67805/PPQ]
- European Commission
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Metal-organic framework [Fe(BTC) (BTC=1,3,5-benzenetricarboxylic acid)] is a convenient heterogeneous catalyst for the carbon-carbon bond forming reaction in toluene between acetophenone and benzaldehyde to give selectively chalcone in high yield. Fe(BTC) appears as a general catalyst rivatives bearing various functionalities. Fe(BTC) could be recycled with no significant loss of catalytic efficiency and crystallinity in subsequent runs.
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