Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 3, Pages 308-312Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800536
Keywords
asymmetric catalysis; bisoxazolines; Stevens rearrangement; ylides
Categories
Funding
- National Natural Science Foundation of China
- Major State Basic Research Development Program [2006CB806105]
- Chinese Academy of Sciences
- Science and Technology Commission of Shanghai Municipality
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The first example of catalytic asymmetric [1,2]-Stevens rearrangement reaction of 1,3-oxathiolanes with diazomalonates has been developed and up to 90% ee is achieved by the bisoxazoline 4e/copper(II) triflate [Cu(OTf)(2)] complex.
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