Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 17, Pages 2903-2911Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900548
Keywords
amine alkylation; amino alcohols; diamines; iridium
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Funding
- NanoCat an International Graduate Program
- Bavarian Elite Graduation Grant
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A highly selective phosphorus/nitrogen (P,N) ligand-based iridium catalyst system efficiently catalyzes the reaction of arylamines with unprotected amino alcohols, yielding N-arylated aliphatic diamines in yields of up to 93%. The reaction can be performed with a wide variety of branched and linear amino alcohols in combination with various aminopyridines or substituted anilines.
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