Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 14-15, Pages 2271-2276Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900362
Keywords
alkynes; hydrazines; metal-organic frameworks; olefins; reduction
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Funding
- Spanish DGI [CTQ06-6857, CTQ2007-67805/PPQ]
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The as-synthesized metal-organic frameworks (MOFs), particularly that based on aluminium coordinated with benzenedicarboxylic acid, constitute selective catalysts for the reduction of carbon-carbon multiple bonds in alkenes, alkynes and alpha,beta-unsaturated esters with hydrazine hydrate in acetonitrile under mild conditions. The present protocol enjoys advantages such as convenient reaction conditions and benign, reusable and cost effective catalyst.
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