Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 9, Pages 1431-1436Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900096
Keywords
C-C coupling; Heck reaction; multi-component reactions; oligoenes; palladium
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Sumitomo Foundation
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The intermolecular three-component coupling of aryl iodides, diarylacetylenes, and alkenes effectively proceeds in the presence of palladium acetylacetonate and silver acetate as catalyst and base, respectively, to give the corresponding 1:2:1 coupling products, 1,3,5-hexatriene derivatives. A further homologation of the oligoene chain of the three-component coupling products by a simple procedure is also presented.
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