4.7 Article

Copper(II)-Catalyzed Aminooxygenation and Carboamination of N-Aryl-2-allylanilines

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 3, Pages 467-471

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800705

Keywords

alkenes; copper; heterocycles; TEMPO

Funding

  1. NIH [NIGMS RO1-GM078383]

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The scope of the intramolecular copper(II)-catalyzed carboamination and aminooxygenation reactions of olefins has been extended to include N-aryl-2-allylanilines. These substrates exhibit divergent reactivity under catalytic vs. stoichiometric conditions.

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