Self-Assembly of Molecules of Metal Macrocyclic Compounds in Nanoreactors on the Basis of Biopolymer-Immobilized Matrix Systems

The problems concerned with the processes of self-assembly of 3d-element aza- and thiazamacrocyclic complexes that happen in nanoreactors on the basis of metal hexacyanoferrate (II) gelatin-immobilized matrices under their contact with water solutions containing various (N, O, S)-donor atomic ligands and organic compounds having one or two carbonyl groups have been considered. It was noted that, in a series of cases, the variety of metal macrocyclic compounds obtained at self-assembly in such specific conditions considerably differs from that of metal macrocycles formed at the conditions traditional for chemical synthesis.