Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 4, Pages 576-582Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800681
Keywords
alkynes; cyclization; gold; heterocycles; homogeneous catalysis; KITPHOS
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Funding
- Umicore AG Co.
- Deutsche Forschungsgemeinschaft [1932/10-1]
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Gold (I)-triflimide (AuNTf(2))complexes of H-KITPHOS and o-MeO-KITPHOS have been prepared and shown to be efficient catalysts for a range of intramolecular cyclisations to afford phenols, acylindenes, alkylidene oxazoles, tetrahydropyrans and lactones, in the majority of cases these catalysts are superior to those previously reported.
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