Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 9, Pages 1423-1430Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900051
Keywords
asymmetric hydrogenation; homogeneous catalysis; phosphonates; rhodium
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The rhodium-catalyzed asymmetric hydrogenation of readily available alpha,beta-unsaturated ester-phosphonates affords the corresponding alpha-chiral phosphonates in excellent yield and ee. The resulting products are useful multifunctional building blocks applied in the synthesis of physiologically active compounds.
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