Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 4, Pages 630-634Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800703
Keywords
alkylindium reagents; arylzinc reagents; cross-coupling reaction; palladium
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Funding
- National Natural Science Foundation of China [20502020, 20702040]
- Wuhan University
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Using desyl chloride (2-chloro-1,2-diphenylethanone) as the oxidant, the palladium-catalyzed reaction of arylzinc with alkylindium reagents occurred smoothly in a highly selective manner to afford the products in 57-90% yields. Preliminary kinetic data indicated that alkylindium reagents were highly favored for transmetallation with the alkoxy-palladium moiety.
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