Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 16, Pages 2573-2578Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900347
Keywords
aerobic oxidation; 2,5-diaminobenzoquinones; catalysis; conjugate addition; copper
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Funding
- Korea Research Foundation [KRF-2008-314-C00203]
- Korean Ministry of Education
- National Research Foundation of Korea [2008-314-C00203] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The aerobic oxidation of various hydroquinones was achieved by using copper nanoparticles entrapped in aluminum oxyhydroxide [Cu/AlO(OH)] at room temperature. Furthermore, 2,5diamino-1,4-benzoquinones were synthesized directly from hydroquinone and amines by a one-pot procedure consisting of the copper-catalyzed aerobic oxidation of hydroquinones and the double addition of amines to the resulting quinones.
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