Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 17, Pages 2845-2849Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900561
Keywords
C-C bond formation; C-H bond activation; cross-dehydrogenative-coupling (CDC) reaction; indolation; palladium catalysis
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Funding
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20060335036]
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An efficient oxidative cross-coupling reaction between 1,3-diarylpropenes and indoles in the presence of palladium chloride was achieved with 2,3-dichloro-5,6-dicyanoquinone (DDQ) as oxidant. The reaction afforded 1,3-diphenylallylindoles in moderate to high yields under mild conditions, thus providing a novel methodology to synthesize the respective products.
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