Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 14-15, Pages 2295-2300Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900479
Keywords
homogeneous catalysis; propargylation; synthetic methods; titanium
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Funding
- Spanish Ministry of Science and Innovation (MICINN) [CTQ2008-06790]
- Regional Government of Andalucia [P05-FQM-1111, FQM339]
- University of Granada
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We describe a novel method for the propargylation of a wide range of aldehydes and ketones catalyzed by titanocene(III) complexes under mild reaction conditions and compatible with many functional groups. Homopropargylic alcohols are obtained as the sole products even when ketones are used as starting materials, which is unusual in Barbier-type propargylations.
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