Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 16, Pages 2650-2656Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900370
Keywords
fatty acids; immobilization; metathesis; nanoparticles; ruthenium; supported catalysts
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Funding
- Institute of Chemical and Engineering Sciences (ICES), Singapore
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The Hoveyda-Grubbs catalyst has been successfully immobilized on surface-modified magnetic nanoparticles with a loading amount of 0.28 mmol ruthenium/g (magnetic support). The supported catalysts were active for the self-metathesis of methyl oleate and macro-monomer in a quantitative conversion, respectively. In addition, the catalyst can be easily separated by using a magnet and reused several times with sustained activity.
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