4.7 Article

Nickel-catalyzed highly selective hydrovinylation of alpha-ketals of vinylarenes

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 10, Pages 1507-1510

Publisher

WILEY-BLACKWELL
DOI: 10.1002/adsc.200800158

Keywords

c-C bond formation; functionalized; olefins; hydrovinylation; nickel

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A nickel-catalyzed hydrovinylation of uketal derivatives of vinylarenes has been developed, providing a new method for preparing functional olefins with a quarternary carbon center in high yields and selectivities.

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