4.7 Article

Eco-Friendly Olefin Dihydroxylation Catalyzed by Diphenyl Diselenide

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 18, Pages 2881-2884

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800571

Keywords

alkenes; catalysis; hydrogen peroxide; hydroxylation; selenium

Funding

  1. MIUR
  2. National Projects [PRIN2005]
  3. Consorzio CINMPIS
  4. Bari
  5. University of Perugia

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The first general and efficient diphenyl diselenide-catalyzed dihydroxylation of double bonds is presented. Hydrogen peroxide can be used as the oxidizing agent, affording generally good yields and high diasteroselectivity.

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