Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 11-12, Pages 1771-1775Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800359
Keywords
allylic substitution; aqueous media; asymmetric catalysis; combinatorial chemistry; palladium; polymer-supported catalyst
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Funding
- JST
- MEXT [460]
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An amphiphilic polystyrene-poly ethylene glycol (PS-PEG) resin-supported ruthenium complex was designed and prepared. The polymeric Ru complex was found to promote the transition metal-catalyzed atom transfer radical addition of halogenated compounds to olefins, the Kharasch reaction, in water under heterogeneous as well as AIBN-free conditions with a high level of atom economy to meet green chemical requirements.
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