Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 11-12, Pages 1850-1854Publisher
WILEY-BLACKWELL
DOI: 10.1002/adsc.200800301
Keywords
2-alkynylbenzaldoximes; cross-coupling reaction; electrophilic cyclization; isoquinoline N-oxides
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Funding
- National Natural Science Foundation of China [20772018]
- Shanghai Pujiang Program
- Program for New Century Excellent Talents in University [NCET-07-0208]
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Electrophilic cyclization of 2-alkynylbenzaldoximes with various electrophiles leads to the formation of 4-iodoisoquinoline N-oxides or 4-bromo-isoquinoline N-oxides under mild conditions. The reaction can be transferred to highly functionalized isoquinoline N-oxides via palladium-catalyzed cross-coupling reactions.
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