Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 11-12, Pages 1696-1700Publisher
WILEY-BLACKWELL
DOI: 10.1002/adsc.200800190
Keywords
bromodimethylsufonium bromide (BDMS); glycosylation; oligosaccharides; promoter; thioglycosides
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Funding
- National Natural Science Foundation of China
- Ministry of Science and Technology of China [973, 863]
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Bromodimethylsulfonium bromide (BDMS) in combination with silver triflate provides a very efficient thiophilic promoter system, capable of activating both disarmed and armed thioglycosides for glycosidic bond formation. The usefulness of this new promoter is illustrated by a successful reactivity-based one-pot oligosaccharide assembly.
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