4.7 Article

Efficient synthesis of substituted selenophenes based on the first palladium(0)-catalyzed cross-coupling reactions of tetrabromoselenophene

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 13, Pages 2109-2117

Publisher

WILEY-BLACKWELL
DOI: 10.1002/adsc.200800316

Keywords

cross-coupling; heterocycles; P ligands; palladium; selenium

Funding

  1. State of Vietnam

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Regioselective Suzuki cross-coupling reactions of tetrabromoselenophene allow a convenient synthesis of aryl-substituted selenophenes. High yields were obtained using a novel biaryl-monophosphine ligand. The first tetra (1-alkynyl)selenophene was prepared in one step by a Sonogashira reaction of tetrabromoselenophene.

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