Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 351, Issue 1-2, Pages 260-270Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800631
Keywords
arylboronic acids; asymmetric catalysis; asymmetric synthesis; diarylamines; N-sulfonylaldimines
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [18064007, B01]
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A chiral N-linked C-2-symmetric bidentate phosphoramidite (N-Me-BIPAM) was newly developed for the rhodium-catalyzed enantioselective addition of arylboronic acids to N-sulfonylimines. This ligand achieved high enantioselectivities in a range of 84-99% ee in additions of arylboronic acids to N-tosyl- and N-nosylarylaldimines.
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