Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 5, Pages 741-748Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800016
Keywords
arylation; C-C coupling; C-H activation; palladium; triazoles
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Generally applicable, palladium-catalyzed direct arylations of 1,2,3-triazoles with aryl chlorides were accomplished through conventional heating at reaction temperatures of 105-120 degrees C. Thereby, intra- and intermolecular C-H bond functionalizations were achieved with a variety of differently substituted chlorides as electrophiles, bearing numerous valuable functional groups.
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