Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 7-8, Pages 995-1000Publisher
WILEY-BLACKWELL
DOI: 10.1002/adsc.200700558
Keywords
aliphatic ketones; beta-cyclodextrin; enantioselective reduction; ruthenium; transfer hydrogenation
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Ruthenium-eta-arene complexes attached to the secondary face of beta-cyclodextrin catalyze the enantioselective reduction (ee up to 98%) of aliphatic and aromatic ketones in aqueous medium in the presence of sodium formate (HCOONa).
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