4.7 Article

Efficient Phosphorus Catalysts for the Halogen-Exchange (Halex) Reaction

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 17, Pages 2677-2682

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800428

Keywords

arylation; catalysts; fluorination; halogen exchange (Halex) reaction; phosphorus

Funding

  1. Ministere de l'Education Nationale for a PhD
  2. Ministry of Science and Information Society Technologies Poland [No 3 TO 9 A 158 29]
  3. LEA (Laboratoire Europeen Associe, Toulouse-Lodz)

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New families of monomeric to dendritic, and monocationic to multicationic (PNP) compounds have been prepared and tested as catalysts in halogen exchange (Halex) reactions. Some of them allow an increase in the efficiency of these reactions which are performed in some cases under the mildest conditions reported up to now.

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