4.7 Article

Catalytic dehydrogenation of o-alkylated or o-alkoxylated iodoarenes with concomitant hydrogenolysis

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 4, Pages 565-569

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200700562

Keywords

catalysis; C-H activation; dehydrogenation; palladium

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Palladium-catalyzed dehydrogenation of suitable chains bonded to an ortho position of an iodoarene has been achieved by two methods both involving oxidative addition of the iodoarene to palladium(0) and palladacycle formation under mild conditions.

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